Effective isotropic potential for dipolar hard spheres
نویسندگان
چکیده
منابع مشابه
Model energy landscapes of low-temperature fluids: Dipolar hard spheres.
An analytical model of non-Gaussian energy landscape of low-temperature fluids is developed based on the thermodynamics of the fluid of dipolar hard spheres. The entire excitation profile of the liquid, from the high-temperature liquid to the point of ideal-glass transition, has been obtained from Monte Carlo simulations. The fluid of dipolar hard spheres loses stability close to the point of i...
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We study the phase behavior of hard and soft spheres with a fixed dipole moment using Monte Carlo simulations. The spheres interact via a pair potential that is a sum of a hard-core Yukawa (or screened-Coulomb) repulsion and a dipole-dipole interaction. The system can be used to model colloids in an external electric or magnetic field. Two cases are considered: (i) colloids without charge (or d...
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We report accurate calculations of the particle density of states in the dipolar hard-sphere fluid. Implementing efficient and tailored Monte Carlo algorithms, we are able to explore, in equilibrium, the low temperature region where a phase separation between a dilute gas of chain ends and a high-density liquid of chain junctions has been predicted to occur. Our data clearly show that the densi...
متن کاملDemixing in binary mixtures of apolar and dipolar hard spheres.
We study the demixing transition of mixtures of equal size hard spheres and dipolar hard spheres using computer simulation and integral equation theories. Calculations are carried out at constant pressure, and it is found that there is a strong correlation between the total density and the composition. The critical temperature and the critical total density are found to increase with pressure. ...
متن کاملA New Mixing Rule for Mixtures of Hard Spheres
A mixing rule for the mixtures of hard-spheres is presented which can be reduced to the standard van der Waals mixing rule at low densities. The effectiveness of the mixing rule for the size and energy parameters of lennard-Jones fluid are examined by combining them with an equation of state to calculate thermodynamic properties. The results of calculation are compared with the molecular dy...
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ژورنال
عنوان ژورنال: Journal of Physics: Condensed Matter
سال: 2013
ISSN: 0953-8984,1361-648X
DOI: 10.1088/0953-8984/25/19/195102